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41.
Acetyl Methyl Torsion in N‐Ethylacetamide: A Challenge for Microwave Spectroscopy and Quantum Chemistry 下载免费PDF全文
Raphaela Kannengießer Marcel J. Lach Prof. Dr. Wolfgang Stahl Dr. Ha Vinh Lam Nguyen 《Chemphyschem》2015,16(9):1906-1911
The gas‐phase structures and parameters describing acetyl methyl torsion of N‐ethylacetamide are determined with high accuracy, using a combination of molecular beam Fourier‐transform microwave spectroscopy and quantum chemical calculations. Conformational studies at the MP2 level of theory yield four minima on the energy surface. The most energetically favorable conformer, which possesses C1 symmetry, is assigned. Due to the torsional barrier of 73.4782(1) cm?1 of the acetyl methyl group, fine splitting up to 4.9 GHz is found in the spectrum. The conformational structure is not only confirmed by the rotational constants, but also by the orientation of the internal rotor. The 14N quadrupole hyperfine splittings are analyzed and the deduced coupling constants are compared with the calculated values. 相似文献
42.
43.
Tam T. T. N. Nguyen Jesper Østergaard Bente Gammelgaard 《Analytical and bioanalytical chemistry》2015,407(28):8497-8503
44.
N. A. Nguyen S. Olaru P. Rodriguez-Ayerbe M. Hovd I. Necoara 《Journal of Optimization Theory and Applications》2017,172(2):623-648
Parametric convex programming has received a lot of attention, since it has many applications in chemical engineering, control engineering, signal processing, etc. Further, inverse optimality plays an important role in many contexts, e.g., image processing, motion planning. This paper introduces a constructive solution of the inverse optimality problem for the class of continuous piecewise affine functions. The main idea is based on the convex lifting concept. Accordingly, an algorithm to construct convex liftings of a given convexly liftable partition will be put forward. Following this idea, an important result will be presented in this article: Any continuous piecewise affine function defined over a polytopic partition is the solution of a parametric linear/quadratic programming problem. Regarding linear optimal control, it will be shown that any continuous piecewise affine control law can be obtained via a linear optimal control problem with the control horizon at most equal to 2 prediction steps. 相似文献
45.
Nguyen Thi Hoai 《Journal of Optimization Theory and Applications》2017,175(2):324-340
Using the direct scheme method, we construct an asymptotic expansion for the solution of a singularly perturbed optimal problem in critical case with cheap control and two fixed end-points. The asymptotic solution contains the outer series and two boundary-layer series in the vicinities of the two end-points. The error estimates for state and control variables and the functional are obtained. It is shown that the value of minimized functional does not increase when a higher-order approximation to the optimal control is used. An illustrative example is given. 相似文献
46.
Vu Thi Huong Jen-Chih Yao Nguyen Dong Yen 《Journal of Optimization Theory and Applications》2017,174(2):567-612
We present a continuous-time generalization of the seminal research and development model of d’Aspremont and Jacquemin (Am Econ Rev 78(5):1133–1137, 1988) to examine the trade-off between the benefits of allowing firms to cooperate in research and the corresponding increased potential for product market collusion. We show the existence of a solution to the optimal investment problem using a combination of results from viscosity theory and the theory of planar dynamical systems. In particular, we show that there is a critical level of marginal cost at which firms are indifferent between doing nothing and starting to develop the technology. We find that colluding firms develop further a wider range of initial technologies, pursue innovations more quickly, and are less likely to abandon a technology. Product market collusion could thus yield higher total surplus. 相似文献
47.
Le Quang Thuy Bui Thi Thanh Nguyen Thi Toan 《Journal of Optimization Theory and Applications》2017,173(2):421-442
Motivated by our recent works on optimality conditions in discrete optimal control problems under a nonconvex cost function, in this paper, we study second-order necessary and sufficient optimality conditions for a discrete optimal control problem with a nonconvex cost function and state-control constraints. By establishing an abstract result on second-order optimality conditions for a mathematical programming problem, we derive second-order necessary and sufficient optimality conditions for a discrete optimal control problem. Using a common critical cone for both the second-order necessary and sufficient optimality conditions, we obtain “no-gap” between second-order optimality conditions. 相似文献
48.
Le Thi Phuong Ngoc Nguyen Anh Triet Alain Pham Ngoc Dinh 《Numerical Functional Analysis & Optimization》2017,38(9):1173-1207
In this paper, we consider a wave equation with integral nonlocal boundary conditions of memory type. First, we establish two local existence theorems by using Faedo–Galerkin method and standard arguments of density. Next, we give a su?cient condition to guarantee the global existence and exponential decay of weak solutions. Finally, we present numerical results. 相似文献
49.
Dang Hai Nguyen George Yin Chao Zhu 《Stochastic Processes and their Applications》2017,127(10):3135-3158
This work is devoted to switching diffusions that have two components (a continuous component and a discrete component). Different from the so-called Markovian switching diffusions, in the setup, the discrete component (the switching) depends on the continuous component (the diffusion process). The objective of this paper is to provide a number of properties related to the well posedness. First, the differentiability with respect to initial data of the continuous component is established. Then, further properties including uniform continuity with respect to initial data, and smoothness of certain functionals are obtained. Moreover, Feller property is obtained under only local Lipschitz continuity. Finally, an example of Lotka–Volterra model under regime switching is provided as an illustration. 相似文献
50.
Nonnegative matrix factorization (NMF) is a powerful technique for dimension reduction, extracting latent factors and learning part-based representation. For large datasets, NMF performance depends on some major issues such as fast algorithms, fully parallel distributed feasibility and limited internal memory. This research designs a fast fully parallel and distributed algorithm using limited internal memory to reach high NMF performance for large datasets. Specially, we propose a flexible accelerated algorithm for NMF with all its \(L_1\) \(L_2\) regularized variants based on full decomposition, which is a combination of exact line search, greedy coordinate descent, and accelerated search. The proposed algorithm takes advantages of these algorithms to converges linearly at an over-bounded rate \((1-\frac{\mu }{L})(1 - \frac{\mu }{rL})^{2r}\) in optimizing each factor matrix when fixing the other factor one in the sub-space of passive variables, where r is the number of latent components, and \(\mu \) and L are bounded as \(\frac{1}{2} \le \mu \le L \le r\). In addition, the algorithm can exploit the data sparseness to run on large datasets with limited internal memory of machines, which is is advanced compared to fast block coordinate descent methods and accelerated methods. Our experimental results are highly competitive with seven state-of-the-art methods about three significant aspects of convergence, optimality and average of the iteration numbers. 相似文献